C...H...N Hydrogen Bond Formation in Trimethylamine Dimer upon One-Photon Ionization

Details C...H...N Hydrogen Bond Formation in Trimethylamine Dimer upon One-Photon Ionization C...H...N Hydrogen Bond Formation in Trimethylamine Dimer upon One-Photon Ionization

Jun 2011

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..confemg08n&link_type=abstract

"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec

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Infrared/Raman

Scientific paper

Structures of trimethylamine dimer cluster cations which are generated by the vacuum-ultraviolet photoionization are investigated by a combination of infrared spectroscopic methods and theoretical reaction-pass calculations. In the trimethylamine dimer cluster cation, a proton of a methyl group is shared with the N atom of the other trimethylamine moiety. This is evidence that the methyl group acts as a proton donor in the cation state.

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