Bubble growth in highly viscous silicate melts during continuous decompression from high pressure

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Scientific paper

High melt viscosity is thought to hinder bubble growth in water-bearing silicate melts, and viscosities above ~10 9 Pa s may prevent growth and viscously quench a bubbly liquid. To investigate the influence of melt viscosity ( ) on magma degassing, rhyolitic melts were experimentally saturated with water at high pressures and then decompressed at a rate of either 0.125 or 0.25 MPa s -1 ; viscosity ( = 2.5 × 10 6 -6.3 × 10 8 Pa s) was varied between experiments by changing the initial hydration pressures and temperatures. Dissolved water contents and bubble sizes and porosities indicate that melts degassed in equilibrium when = 2.5 × 10 6 Pa s, whereas when > 10 8 Pa s, the melts did not degas at all, despite pressure drops up to 50 MPa. The transition between efficient and inefficient degassing occurred when = ~10 7-8 Pa s. In all experiments, bubbles expanded in size in response to pressure drops, but the extent of expansion and the size of bubbles that expanded both decreased as viscosity increased (e.g., 0-40 m bubbles expanded when = 1.6 × 10 8 Pa s; 0-20 m bubbles expanded when = 6.3 × 10 8 Pa s). The shift from efficient to inefficient degassing probably resulted from the decrease in water diffusivity ( D H 2 O ) as temperature decreased, whereas the decrease in degree of bubble expansion at higher viscosities resulted from increasing viscous resistance. Our results confirm model predictions that bubble expansion will be arrested when ~10 9 Pa s, at decompression rates of 0.125 and 0.25 MPa s -1 . Such rates are expected only in explosive volcanic eruptions, however, and so higher viscosities will be needed for the melt to resist bubble growth in effusive eruptions.

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