Branching ratio for the ^5S_2^o-^3P_2,1 inter-system resonance multiplet in P II

Astronomy and Astrophysics – Astrophysics

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Atomic Data, Methods: Laboratory

Scientific paper

The P II inter-system multiplet, 3s3p(3\) (5S_2^o\) -\ 3s(23p^2\) (3P_{2,1}) at lambda_ {air} = 221.033nm and 219.556nm, have been observed in emission from a low-pressure inductively-coupled plasma source. The measured branching ratio, A2210/A2196 =3.04+/- 0.15, is in agreement with recent ab initio calculations. Absolute transition probabilities, A2210=4500+/- 330 s(-1) and A2196=1480+/- 120 s(-1) , are determined by combining the measured branching ratio with the previously measured lifetime of the (5S_2^o) metastable level.

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