Boron systematics of authigenic carbonates: a new approach to identify fluid processes in accretionary prisms

Other

Scientific paper

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

4

Scientific paper

Boron contents and boron, carbon and oxygen stable isotopes were determined for authigenic carbonates recovered from Ocean Drilling Program Leg 146, Oregon margin. Carbonate precipitates are the most widespread authigenic phase in the shallow accretionary wedge and carry chemical information about long-term variations in pore fluid origin and flow paths in the Cascadia subduction zone. Drilling the first ridge (toe area including the frontal thrust) and the second ridge (or Hydrate Ridge) of the prism demonstrated different fluid regimes, with higher B contents in the authigenic precipitates at the toe. The δ11B of 18 authigenic precipitates analysed ranges from 13.9‰ to as high as 39.8‰, extending the upper range of previously reported carbonate δ11B values considerably. When related to the δ11B ratio of their parent solutions, these data are characteristic of fluid-related processes in accretionary prisms. Together with δ13C and δ18O, δ11B ratios of the carbonate concretions, nodules and crusts allow one to distinguish between precipitation influenced by (i) seawater, (ii) fluid reservoirs at different depth levels within the accretionary prism and (iii) cage water from dissociated gas hydrates, the latter possibly indicating a fluctuation of the bottom simulating reflector during most recent Earth's history. From this first systematic boron study on authigenic precipitates from an accretionary prism it is suggested that B contents of such carbonate crusts and concretions exceed those reported for other marine carbonates. Given the abundance of such precipitates at convergent margins, they represent a significant B sink in geochemical cycling. Isotopic compositions of the parent fluids to the carbonates mirror B chemistry of modern pore waters from convergent margins. The precipitates carry information of different subduction-related fluid processes over a certain period of time, and hence are a crucial tracer in the investigation of palaeo-fluid flow.

No associations

LandOfFree

Say what you really think

Search LandOfFree.com for scientists and scientific papers. Rate them and share your experience with other people.

Rating

Boron systematics of authigenic carbonates: a new approach to identify fluid processes in accretionary prisms does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Boron systematics of authigenic carbonates: a new approach to identify fluid processes in accretionary prisms, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Boron systematics of authigenic carbonates: a new approach to identify fluid processes in accretionary prisms will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFWR-SCP-O-1184861

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.