Bands of H3+ up to 4ν2: Rovibrational transitions from first principles calculations

Astronomy and Astrophysics – Astrophysics

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Scientific paper

Band origins and Einstein A coefficients are presented for transitions linking all the vibrational levels of H3+ up to 4ν2(l = 4). The importance of these data for astrophysical modeling is discussed. For H3+, rovibrational wavefunctions and energy levels are obtained for J up to 16. These are used to synthesize sample rovibrational spectra with particular emphasis on the ν1 + 2ν2(l = 2) <-- 0 and 4ν2(l = 2) <-- 0 bands, which would appear to be good candidates for laboratory observation.

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