Authigenic carbonates in sediments from the Gulf of Mexico

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Scientific paper

The carbon isotopic composition of diagenetic dolomite and calcite in some sediments of the Gulf of Mexico varies between ``normal-marine'' (δ13C ca. 0‰) and -14.6‰ which suggests that biogenic CO2 contributed to the carbonate formation. The δ13O values of dolomite and coexisting calcite are very similar but variable down-core.
Dolomite and calcite precipitated early from pore water where SO42- was not reduced. However, during (and after?) SO42- reduction dolomite and calcite still formed and there are at least two generations of carbonate minerals present.

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