Atmospheric Chemistry of Iron, Magnesium, and Silicon in Substellar Objects

Astronomy and Astrophysics – Astronomy

Scientific paper

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Scientific paper

We use thermochemical equilibrium calculations to model Fe, Mg, and Si chemistry in the atmospheres of giant planets, brown dwarfs, and extrasolar giant planets. The chemical behavior of individual Fe, Mg, and Si gases and condensates is determined as a function of temperature, pressure, and metallicity. Our results are therefore, in principle, independent of any particular model atmospheric profile. The chemistry of these elements is very strongly effected by the condensation of iron metal, forsterite, and enstatite, which are expected to produce the most massive cloud layers in substellar atmospheres. Our model results are used to identify gases which may serve as indicators of weather, to predict the chemical composition of cloud layers, and to provide constraints for composition, structure, and opacity in the atmospheres of substellar objects.

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