Analysis of the Comet-Tail (A2Πi-X2Σ+) Bands of 13C16O+

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Scientific paper

In the electronic emission spectrum of the isotopic carbon monoxide ion 13C16O+ molecule, seven bands of the comet-tail (A2Πi-X2Σ+) system have been recorded and analyzed. The spin splitting in most observed lines of the bands 1-0, 2-0, 3-0, 4-0, 5-0, 2-1, and 7-1 comprising over 1900 lines has been recorded under high resolution by using conventional spectroscopy. The rotational analysis of bands has been performed by nonlinear least-squares procedures and by means of effective Hamiltonians of Brown et al., the rovibronic structure parameters have been obtained. As a result of multistaged and merged analysis of the currently obtained bands of the A-X system and of the bands of the B-X system obtained earlier the state of information about the energy structure has been significantly enlarged for the A state and enlarged and improved for the X state. Also RKR potential curves have been calculated for both states and Franck-Condon factors as well as r-centroids of the comet-tail system of 13C16O+.

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