Analysis of the 2ν1+2ν3 band of ozone: line positions and intensities.

Details Analysis of the 2ν1+2ν3 band of ozone: line positions and intensities. Analysis of the 2ν1+2ν3 band of ozone: line positions and intensities.

Apr 1996

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1996jqsrt..55..449b&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 55, issue 4, pp. 449-455

Computer Science

12

Ozone: Infrared Spectra, Ozone: Laboratory Spectra

Scientific paper

The 2ν1+2ν3 band of ozone, appearing in the 4150 cm-1 region has been observed for the first time, using the high resolution Reims FTS and a large p×l product of 3616 cm×48 torr. 275 transitions have been assigned, involving J and Ka up to 55 and 9, respectively. The fit on the 193 corresponding energy levels using single Watson type Hamiltonian leads to a standard deviation of 1.4×10-3cm-1 on the order of experimental accuracy. Line intensities are also measured and calculated with suitable transition moment operators. The authors report here the set of parameters as well as transition moment operators. A complete list, with a cut-off of: 1×10-26cm-1/mol.cm-1 has been generated which leads to a band intensity Sv(2ν1+2ν3) = 1.175×10-22cm-1/mol.cm-2.

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