An isotopic study of siderites, dolomites and ankerites at high temperatures

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Scientific paper

Siderite, dolomite and ankerite were reacted with ">103°" phosphoric acid at temperatures up to 150°C with >99° yields achieved in less than two hours, using a modification of the McCrea (1950) technique. The oxygen fractionation factors, , between the 18 O of the carbonate and that of the acid-extracted CO 2 are: An empirically derived relationship between the chemical composition of a carbonate in the CaCO 3 -(Ca, Mg)(CO 3 ) 2 -FeCO 3 system and the function 10 3 In at 100°C is 10 3 In = 8.94 X CaCO 3 + 9.29 X MgCO 3 + 8.77 X FeCO 3 where X i is the mole percent of component i in the carbonate.

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