An experimental study on kinetically-driven precipitation of calcium-magnesium-iron carbonates from solution: Implications for the low-temperature formation of carbonates in martian meteorite Allan Hills 84001

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Spherical carbonate globules of similar composition, size, and radial Ca-, Mg- and Fe-zonation to those in Martian meteorite ALH84001 were precipitated from Mg-rich, supersaturated solutions of Ca-Mg-Fe-CO2-H2O at 150(C. The supersaturated solutions (pH ( 6-7) were prepared at room temperature and contained in Teflon(tm)-lined stainless steel vessels, which were sealed and heated to 150(C for 24 hr. Experiments were also conducted at 25(C and no globules comparable to those of ALH84001 were precipitated. Instead, amorphous Fe-rich carbonates were formed after 24 hours and Mg-Fe calcites formed after 96 hours. These experiments suggest a possible low-temperature, inorganic origin for the carbonates in Martian meteorite ALH84001.

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