Computer Science
Scientific paper
Apr 2010
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010e%26psl.293..114y&link_type=abstract
Earth and Planetary Science Letters, Volume 293, Issue 1-2, p. 114-120.
Computer Science
5
Scientific paper
Reliable reconstructions of deep ocean carbonate ion concentration, [CO32-], and pH are crucial to understand mechanisms responsible for the past atmospheric CO2 variations observed in ice cores. However, it is challenging to reconstruct past deep water [CO32-] and pH and literature results from different proxies conflict, warranting careful investigations on possible reasons for the existing inconsistencies. Here, we present the first down core B/Ca and δ11B records measured in an epifaunal benthic foraminifer Cibicidoides wuellerstorfi from the Caribbean Sea during the last 160 kyr. The two proxies yield quantitatively comparable deep water [CO32-] and pH results, showing high values during glacials relative to inter-glacials (differences in [CO32-] and pH are ˜ 35 μmol/kg and ˜ 0.15, respectively), consistent with past ocean circulation changes in the Caribbean Sea. Our data provide convincing evidence that both proxies serve as faithful proxies to estimate deep ocean [CO32-] and pH, despite our incomplete understanding of boron incorporation into foraminiferal carbonates.
Broecker Wallace S.
Clark Elizabeth
Elderfield Henry
Foster Gavin L.
Yu Jimin
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