An equilibrium speciation model for copper in sea and estuarine waters at 25°C including complexation with glycine, EDTA and NTA

Computer Science

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Scientific paper

An equilibrium speciation model has been derived for copper, glycine, EDTA and NTA in sea and estuarine waters. The model is based on the ion-pairing model of and (1981) for the major components of seawater, and the derivation has taken advantage of recent measurements on many of the interactions involved. The model is intended for use in the calibration of complexation capacity methods, and in the interpretation of bioassay measurements. Fitting functions for the apparent association constants of the organic acids as a function of salinity have been derived, and selected speciation calculations from the literature have been reassessed.

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