An algorithm for finding composition, molar volume and isochors of CO 2 -CH 4 fluid inclusions from T h and T fm (for T h < T fm )

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Scientific paper

A modified Redlich-Kwong equation of state is used to calculate the solubility of CO 2 in methane at various temperatures and pressures. From the solubility of CO 2 in CH 4 at the triple point and at final melting ( T h < T fm ), and the molar volume of solid CO 2 , the volume of solid at the triple point, and the molar volume of the inclusion can be calculated using a mass balance. The pressure at the melting point is calculated from the equation of state. The algorithm predicts composition, molar volume, pressure at final melting and the isochor pressure (for a given temperature of trapping) for CO 2 -CH 4 fluid inclusions for the case T h < T fm , given T h , T fm and experimental data on P h and d co 2 (solid) at T h .

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