An additional uncertainty in calculated radiative association rates of molecular formation at low temperatures

Astronomy and Astrophysics – Astrophysics

Scientific paper

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19

Association Reactions, Interstellar Chemistry, Reaction Kinetics, Molecular Clouds, Quantum Mechanics

Scientific paper

The effect of introducing a centrifugal barrier correction to a
previously published theory of radiative association rate coefficients
for polyatomic products is demonstrated. Discrepancies of up to one
order of magnitude from an earlier calculated rate coefficient are
found.

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