Accurate Laboratory Wavelengths of the Vacuum Ultraviolet A(v'=3)-X(v''=0) Band of 12C17O and 12C18O

Astronomy and Astrophysics – Astronomy

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Ism: Molecules, Methods: Laboratory, Molecular Data, Ultraviolet: General

Scientific paper

Six individual rotational lines (J''<=3) of 12C17O, as well as four of 12C18O, were detected in the A1Π(v'=3)-X1Σ+(v''=0) vibronic band, and their wavelengths determined using neighboring 12C16O and 13C16O lines as reference. The measurements (fluorescence excitation spectra) were performed in a pulsed supersonic jet (Ar or Ne as carrier gas) employing a tunable pulsed vacuum ultraviolet radiation source with a narrow bandwidth (~5 GHz). The new spectral data on 12C17O and 12C18O are applied to the interpretation of recent vacuum ultraviolet observations of 12C17O and 12C18O in the interstellar medium.

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