Absorption spectrum of Pb I between 1350 and 2041 A

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Absorption Spectra, Autoionization, Iodides, Lead Compounds, Optical Transition, Ultraviolet Absorption, Electron Transitions, Lead Isotopes, Line Spectra, Molecular Energy Levels, Nuclear Spin, Quadrupoles, Tables (Data)

Scientific paper

The high resolution absorption spectrum of Pb I is reported between 1350 and 2041 A. Transitions are observed from the 6p2 (1/2,1/2)0, (3/2,1/2)1, and (3/2,1/2)2 levels to levels with J less than or equal to 2 associated with 6pns and 6pnd configurations. Energy levels have been determined with n(asterisk) values as high as 74. More than 500 spectral features and 370 odd parity energy levels are reported, a major part of which are new. These observations include five electric quadrupole transitions and 31 nuclear-spin-induced transitions from the Pb-207 isotope. Ionization limits of 59819.57 per cm and 73900.64 per cm have been determined for levels converging on the 6p 2P(1/2)O and 6p 2P(3/2)O levels of Pb II, respectively. An analysis of these data in terms of Lu-Fano graphical methods and multichannel quantum defect parametrization also is presented.

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