Absorption coefficients for water vapor at 193 nm from 300 to 1073 K

Details Absorption coefficients for water vapor at 193 nm from 300 to 1073 K Absorption coefficients for water vapor at 193 nm from 300 to 1073 K

Jul 1993

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1993jqsrt..50...39k&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer (ISSN 0022-4073), vol. 50, no. 1, p. 39-46.

Computer Science

4

Absorptivity, Molecular Excitation, Photodissociation, Ultraviolet Absorption, Water Vapor, Absorption Spectra, Franck-Condon Principle, Ultraviolet Spectra

Scientific paper

Measurements of the water absorption coefficient at 193 nm from 300 to 1073 K are reported. The measurements were made using broadband VUV radiation and a monochromator-based detection system. The water vapor was generated by a saturator and metered into a flowing, 99 cm absorption cell via a water vapor mass flow meter. The 193 nm absorption coefficient measurements are compared to room temperature and high temperature shock tube measurements with good agreement. The absorption can be parameterized by a nu3 vibrational mode reaction coordinate and the thermal population of the nu3 mode.

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