Absoption of Spectra of Mercury Halides

Details Absoption of Spectra of Mercury Halides Absoption of Spectra of Mercury Halides

Apr 1945

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1945natur.155..452g&link_type=abstract

Nature, Volume 155, Issue 3937, pp. 452 (1945).

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Scientific paper

RAO1 has recently observed the absorption spectra obtained when halides of mercury were placed in a heated steel tube. New systems attributed to HgCl and HgBr were found and analysed, leading to values for the dissociation energies of these molecules. Comparison of the wave-lengths of these `new' bands with tables2 of collected band heads of known molecules reveals coincidences with CuCl and CuBr. More detailed comparison shows that Rao's Q1 heads of `HgCl' coincide with the D system of CuCl, and the Q2 heads with the E system. For `HgBr' all the assigned band heads can be identified with the E system of CuBr; other unassigned bands of `HgBr' coincide with bands of the A system of CuBr. The identity is quite convincing.

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