Absolute OH absorption cross sections (for lidar measurements)

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Absorption Cross Sections, Hydroxyl Radicals, Molecular Spectra, Optical Radar, Line Spectra, Molecular Rotation, Oscillator Strengths

Scientific paper

Experimental data are employed to calculate absorption cross sections for several rotational lines in the OH A-X system. The cross sections are computed as functions of the spectral and line widths and temperature of a laser beam, and account for lifetimes and branching ratios. Detection limits for the P1(2) transition of the (1,0) band were examined. The oscillator strengths and cross-sections obtained are important for quantifying OH concentrations in the stratosphere from lidar return signals.

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