Absolute intensities for the Q-branch of the 3 nu(sub 2) (-) nu(sub 1) (465.161/cm) band of nitrous oxide

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Atmospheric Chemistry, Dipole Moments, Earth Atmosphere, Nitrous Oxides, Spectral Bands, Vibrational Spectra, Atmospheric Composition, Atmospheric Models, Laser Spectrometers, Semiconductor Lasers, Spectrum Analysis, Tunable Lasers

Scientific paper

The absolute intensities of four lines, Q 15-Q 18 in the 03(sup 1)0-10(sup 0)0 band, of N2O have been measured using a tunable diode laser spectrometer at temperatures between 380 and 420 K and pressures between 4 and 15 torr. Even though these transitions are weak and produced only about 2% of absorption at the line center for a pathlength of 52 m, they were measured with a signal to noise ratio of about 20 due to the high sensitivity of the instrument. The band strength derived is 1.03 x 10(exp -24) cm/molec at 296 K.

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