A valid Margules formulation for an asymmetric ternary solution - Revision of the olivine-ilmenite thermometer, with applications

Computer Science

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Gibbs Free Energy, Ilmenite, Lunar Geology, Olivine, Ternary Systems, Iron Compounds, Iron Oxides, Magnesium Compounds, Rocks, Solid Solutions, Thermometers, Titanium Compounds

Scientific paper

A derivation of a valid asymmetric ternary Margules expression for the excess free energy is presented, and the olivine-ilmenite thermometer is revised accordingly. Although the effect on the thermometer is relatively small, the revision results in improved precision. Estimated temperatures of equilibration are presented for olivine and ilmenite from lunar and terrestrial rocks.

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