Astronomy and Astrophysics – Astrophysics
Scientific paper
Sep 1978
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1978apjs...38...39m&link_type=abstract
Astrophysical Journal Supplement Series, vol. 38, Sept. 1978, p. 39-68. Research supported by the National Research Council of
Astronomy and Astrophysics
Astrophysics
188
Abundance, Interstellar Chemistry, Interstellar Gas, Molecular Gases, Reaction Kinetics, Bibliographies, Gas Composition, Molecular Ions, Molecules, Tables (Data)
Scientific paper
Steady-state abundances are calculated from 455 ion-neutral, neutral-neutral, photodestruction, ion-electron recombination, and cosmic-ray destruction reactions among 100 molecular species formed from the elements H, He, C, N, O, Mg, Si, S, and Fe. Only gas-phase reactions are considered except for grain formation of H2. Results are presented for gas densities of 10 to 1 million per cu cm and a wide range of optical depth. The dependence of the molecule abundances on cosmic element abundances, the interstellar radiation field, kinetic temperature, and cosmic-ray ionization rate is investigated. A comparison with observations of interstellar clouds shows that the standard model employed is clearly inadequate only for CH(+) and HCO, that agreement for H2CO is good at intermediate and high densities, and that the CN abundances at low densities agree well with optical observations. Agreement with observations is found to be satisfactory for CH, C2H, CO, OH, HCN, NH3, HCO(+), and N2H(+).
Ginsburg J. L.
Kuntz P. J.
Mitchell George F.
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