A Simple Model for N2 Line Oscillator Strengths of the b'1Σ+u(1), c'41Σ+u(0), b1Π+u(4), b1Π+u(5), and c31Π+u(0)-X1Σ+g(0) Bands

Details A Simple Model for N2 Line Oscillator Strengths of the b'1Σ+u(1), c'41Σ+u(0), b1Π+u(4), b1Π+u(5), and c31Π+u(0)-X1Σ+g(0) Bands A Simple Model for N2 Line Oscillator Strengths of the b'1Σ+u(1), c'41Σ+u(0), b1Π+u(4), b1Π+u(5), and c31Π+u(0)-X1Σ+g(0) Bands

Jul 2006

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2006apj...645.1560l&link_type=abstract

The Astrophysical Journal, Volume 645, Issue 2, pp. 1560-1567.

Astronomy and Astrophysics

Astronomy

4

Ism: Molecules, Molecular Data, Planets And Satellites: General, Ultraviolet: General

Scientific paper

A simple model, based on fitting experimental energy term values, has been developed to calculate the line oscillator strengths (f) of N 2 b'1Σ+u(1), c'41Σ+u(0), b1Π+u(4), b1Π+u(5), and c31Π+u(0)-X1Σ+g(0) bands. The strong rovibronic coupling among these states leads to quantum interference in the transition dipole matrix elements and results in anomalous P/R branch oscillator strength ratios. The calculated line oscillator strengths are in very good agreement with experimental values. The calculated values can be used for modeling atmospheric emission. Calculated line oscillator strengths for J' up to 30 are provided.

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