Other
Scientific paper
Mar 1989
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1989a%26a...211..413g&link_type=abstract
Astronomy and Astrophysics (ISSN 0004-6361), vol. 211, no. 2, March 1989, p. 413-418. Research supported by the Alexander von Hu
Other
37
Ammonia, Hydrogen, Interstellar Chemistry, Nitrogen Ions, Abundance, Endothermic Reactions
Scientific paper
The initial reaction in the ion-molecule synthesis of ammonia in dense interstellar clouds, N(+) + H2 yields NH(+) + H, is studied using phase space theory. It is found that the reaction is too slow at a temperature of 10 K to explain the ammonia abundance in cool dense interstellar clouds. For a nonthermal translational distribution of N(+) formed from the He(+)-N2 reaction, the results show that the rate at which N(+) is converted into NH(+) is dependent on the nascent N(+) spin-orbit state distribution.
Galloway Eric T.
Herbst Eric
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