Astronomy and Astrophysics – Astrophysics
Scientific paper
Oct 1979
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1979ap%26ss..65..337c&link_type=abstract
(Workshop on Thermodynamics and Kinetics of Dust Formation in the Space Medium, Houston, Tex., Sept. 6-8, 1978.) Astrophysics an
Astronomy and Astrophysics
Astrophysics
4
Coagulation, Cosmic Dust, Interstellar Matter, Nucleation, Clathrates, Clumps, Drops (Liquids), Entropy, Particle Size Distribution
Scientific paper
The paper examines mechanisms of nucleation and growth by condensation and coagulation in the light of recent research on properties of small clusters. Homogeneous, hetero-molecular, and heterogeneous nucleation is analyzed, and expressions for the rate of formation of a stable condensed phase and evaluation of the free energy of formation of charged droplets are given. Application of high-pressure mass spectrometry which makes possible a direct determination of intensity spectra for cluster distributions, measurement of the thermodynamic properties of individual ion clusters and determination of cluster entropy and bond energy is discussed. Finally, coagulation of the condensed phase is considered, noting that concentration and mean particle size vary during coagulation, but the shape distribution is time independent, leading to the concept of a self-preserving aerosol size distribution.
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