A possible deuterium anomaly: Implications of the CH3D/CH4 mixing ratios in the atmospheres of Jupiter, Saturn, and Uranus

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Deuterium Compounds, Jupiter Atmosphere, Methane, Saturn Atmosphere, Uranus Atmosphere, Atmospheric Chemistry, Atmospheric Composition, Chemical Fractionation, Planetary Cores, Planetary Evolution

Scientific paper

Observations of CH3D in the atmospheres of the outer planets provide a test of the theory of deuterium fractionation equilibrium in the formation and evolution of these planets. Recent measurements of the CH3D/CH4 mixing ratios made for Saturn and Uranus are presented and intercompared with current values of Jupiter, illustrating large differences between the planets. Their implied D/H ratios are compared to D/H ratios derived from measurements of HD/H2; and, in the cases of Jupiter and Saturn, they may be incompatible. Implications of these comparisons are discussed in terms of the deuterium fractionation chemistry and possible enrichments of deuterium in the core ices of the planets.

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