A photochemical study of the kinetics of the reactions of NH2 with phosphine, ethylene, and acetylene using flash photolysis-laser induced fluorescence

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Acetylene, Atmospheric Chemistry, Ethylene, Jupiter Atmosphere, Laser Induced Fluorescence, Phosphines, Photochemical Reactions, Reaction Kinetics, Ammonia, Atmospheric Composition, Fluorescence, Jupiter Red Spot, Laser Applications, Photolysis

Scientific paper

The photochemistry of the reactions of NH2 was investigated in an attempt to explain the existence of an abundance of ammonia in the Jovian atmosphere. The production of ammonia reservoirs from the coupling of ammonia with other atmospheric constituents was considered. The rate constants for the reactions of NH2 radicals with phosphine, acetylene, and ethylene were measured. Flash photolysis was used for the production of NH2 radicals and laser induced fluorescence was employed for radical detection. It was determined that the rates of the reactions were too slow to be significant as a source of ammonia reservoirs in the Jovian atmosphere.

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