A new 3 Pi-3 Delta system of the ZrO molecule

Details A new 3 Pi-3 Delta system of the ZrO molecule A new 3 Pi-3 Delta system of the ZrO molecule

Nov 1979

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1979apj...234..401p&link_type=abstract

Astrophysical Journal, Part 1, vol. 234, Nov. 15, 1979, p. 401-406. NSF-supported research.

Astronomy and Astrophysics

Astrophysics

14

Infrared Spectra, Molecular Spectra, Near Infrared Radiation, Spectrum Analysis, Zirconium Oxides, Astrophysics, Gas Discharge Tubes, Interferometry

Scientific paper

Results of an investigation of the infrared spectrum of ZrO which reveal the presence of a new 3 Pi-3 Delta system are presented. ZrO interoferograms and arc spectra from a gas discharge tube were obtained using a large Fourier transform spectrometer. Analysis of the Q branches observed in the interferograms and P and R branches contained in the arc spectra indicate that the Q branch observed at 10684 kaysers is associated with a transition involving the X' 3 Delta 2 substrate, and it is concluded that the upper state of the transition must be 3 Pi from the Lambda-type doubling of the 3 Pi 0 substrate. The R heads of the new system are found to account for four of the seven distinct heads observed in the 9299-9500-A region of the ZrO spectrum, with the remaining three heads probably due to a second system.

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