A multi-step model for the origin of E3 (enstatite) chondrites

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Scientific paper

It appears that the mineralogy and chemical properties of type 3 enstatite chondrites could have been established by fractionation processes (removal of a refractory component, and depletion of water) in the solar nebula, and by equilibration with nebular gas at low-to-intermediate temperatures (~700-950 K). We describe a model for the origin of type 3 enstatite chondrites that for the first time can simultaneously account for the mineral abundances, bulk-chemistry, and phase compositions of these chondrites, by the operation of plausible processes in the solar nebula. This model, which assumes a representative nebular gas pressure of 10-5 bar, entails three steps: (1) initial removal of 56% of the equilibrium condensed phases in a system of solar composition at 1270 K; (2) an average loss of 80-85% water vapor in the remaining gas; and (3) two different closure temperatures for the condensed phases. The first step involves a "refractory-element fractionation" and is needed to account for the overall major-element composition of enstatite chondrites, assuming an initial system with a solar composition. The second step, water-vapor depletion, is needed to stabilize Si-bearing metal, oldhamite, and niningerite, which are characteristic minerals of the enstatite chondrites. Variations in closure temperatures are suggested by the way in which the bulk chemistry and mineral assemblages of predicted condensates change with temperature, and how these parameters correlate with the observations of enstatite chondrites. In general, most phases in type 3 enstatite chondrites appear to have ceased equilibrating with nebular gas at ~900-950 K, except for Fe-metal, which continued to partially react with nebular gas to temperatures as low as ~700 K.

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