a Microwave Investigation of the CO_2-PYRIDINE Van Der Waals Complex

Details a Microwave Investigation of the CO_2-PYRIDINE Van Der Waals Complex a Microwave Investigation of the CO_2-PYRIDINE Van Der Waals Complex

Jun 2009

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2009mss..conferc05d&link_type=abstract

"International Symposium On Molecular Spectroscopy, 64th Meeting, Held 22-26 June, 2009 at Ohio State University. http://molspec

Computer Science

Microwave

Scientific paper

Rotational spectra of the NC_{4}H_{4}-CO_{2} dimer and four isotopologs have been observed using Fourier transform microwave spectroscopy. Analysis of the rotational and quadrupole coupling constants will be presented. Preliminary structural analysis indicates the complex is planar; the CO_{2} axis is perpendicular to the C_{2} axis of pyridine with a C-N van der Waals bond length of 2.83 Å. This complex provides the first step in the microsolvation of an organic solute using CO_{2} as a solvent and therefore may be useful in understanding solute-solvent interactions in supercritical CO_{2}.

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