A laboratory investigation of the production and properties of molecular and radical species pertinent to planetary atmospheres

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Atmospheric Chemistry, Molecular Gases, Planetary Atmospheres, Radicals, Reaction Kinetics, Acetylene, Photodecomposition, Photolysis, Vinyl Radical

Scientific paper

Vinylidene (H2C=C) is shown to be the largest photodecomposition channel in the direct photolysis of both C2H2 and C2H4. The chemistry of H2C=C as it relates to planetary atmospheres is discussed. The vinyl radical (C2H3), important in the acetylene chemistry cycle, has been directly observed spectroscopically and the kinetics of several key reactions of this species measured.

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