A High-Resolution 18O Isotope Study in the Vacuum Ultraviolet of the A 1 Pi X 1 Sigma + 4th Positive System of CO

Details A High-Resolution 18O Isotope Study in the Vacuum Ultraviolet of the A 1 Pi X 1 Sigma + 4th Positive System of CO A High-Resolution 18O Isotope Study in the Vacuum Ultraviolet of the A 1 Pi X 1 Sigma + 4th Positive System of CO

Mar 1997

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1997apjs..109..269b&link_type=abstract

Astrophysical Journal Supplement v.109, p.269

Astronomy and Astrophysics

Astronomy

5

Line: Identification, Methods: Laboratory, Molecular Data, Ultraviolet: General

Scientific paper

High-resolution jet emission spectra of 12C18O in the 1380--1650 A region of the 4th positive bands, A 1 Pi --> X 1 Sigma +, have been recorded photographically and have been reduced to upper-state term values for low to medium rotational quantum numbers in the 10 lowest vibrational levels of A 1 Pi . The de-perturbation of the A state from spin-orbit and rotation-electronic interactions with singlet and triplet Sigma and Delta states has established the percentage 1 Pi character of the observed excited-state rovibronic levels. Dunham series expansion coefficients representing the de-perturbed energies have also been determined.

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