Astronomy and Astrophysics – Astronomy
Scientific paper
Nov 1996
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1996sci...274.1508k&link_type=abstract
Science, Volume 274, Issue 5292, pp. 1508-1511
Astronomy and Astrophysics
Astronomy
72
Scientific paper
The reaction of ground-state carbon atoms with acetylene was studied under single-collision conditions in crossed beam experiments to investigate the chemical dynamics of forming cyclic and linear C_3H isomers (c-C_3H and J-C_3H, respectively) in interstellar environments via an atom-neutral reaction. Combined state-of-the-art ab initio calculations and experimental identification of the carbon-hydrogen exchange channel to both isomers classify this reaction as an important alternative to ion-molecule encounters to synthesize C_3H radicals in the interstellar medium. These findings strongly correlate with astronomical observations and explain a higher [c-C_3H]/[I-C_3H] ratio in the dark cloud TMC-1 than in the carbon star IRC+10216.
Head-Gordon Martin
Kaiser Ralf I.
Lee Yin-Tat
Ochsenfeld C.
Suits Arthur G.
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