A CaAl4O7-bearing refractory spherule from Murchison - Evidence for very high-temperature melting in the solar nebula

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Calcium Oxides, Aluminum Oxides, Mixed Oxides, Murchison Meteorite, High Temperature Environments, Meteoritic Composition, Refractory Materials, Cooling, Scanning Electron Microscopy, Mineralogy, Crystallization, Melting

Scientific paper

Results are presented of analyses (by a SEM equipped with an EDXS system, INAA, and an electron microprobe) of a unique refractory spherule, B6, recovered from the Murchison C2 chondrite. The spinel-, hibonite-, CaAl4O7-, perovskite-bearing spherule appears to have been almost completely molten, requiring exposure to the highest temperature yet inferred for any refractory inclusion. Strong evidence is presented that the spherule crystallized from a liquid. The presence of measurable excess Al2O3 in B6 spinel despite the normal a(Al2O3)/a(MgO) ratio of the inclusion is further evidence of its unusually high temperature history. Despite the high peak temperature, no volatility-derived fractionation of REEs or isotopic fractionation of Mg occurred, probably because cooling was rapid enough for a very rapid formation of a spinel shell which sealed off the molten interior of the inclusion from the nebular gas.

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