3.4 Micron Emission from Aliphatic Hydrocarbons in Proto-Planetary Nebulae

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A family of infrared emission features at 3.3, 6.2, 7.7, 8.6, 11.3 μ m are seen in a variety of objects with strong uv radiation fields. These features are attributed to stretching and bending modes of aromatic compounds. An aliphatic feature has been detected at 3.4 μ m in some of these same objects. Proto-planetary nebulae (PPNs) are in a short-lived stage of evolution between the asymptotic giant branch and planetary nebula (PN) phases. It is observed that in this transitional stage, the strengths of some of these infrared emission features differ from those seen in PNs. In particular, the 3.4 μ m feature, which is usually much weaker than the 3.3 μ m feature, is of comparable strength in some PPNs. To better understand the properties of these features, we carried out medium-resolution (R ~2000) spectroscopy of a sample of PPNs in the 3 μ m region using the NIRSPEC spectrograph on the Keck II telescope. Eight PPNs were observed. These resulted in the first detection of the 3.4 μ m feature in two objects and possible detections in two others and the first detection of the 3.3 μ m feature in two other objects. We will discuss what has been learned from the observations of the 3.4 μ m feature and review the evidence for a correlation of the ratio of the 3.4 to 3.3 μ m features with spectral type. These observations were carried out in the service observing mode as part of a program of limited access to Keck provided to the Gemini Observatory community. This work was funded in part by grants to BJH from the NSF and to SK by NSERC.

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