234 U / 238 U and 230 Th / 234 U activity ratios in the colloidal phases of aquifers in lateritic weathered zones

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Scientific paper

A procedure was developed for comparing solute and colloid phases of groundwaters in contact with uranium ore bodies at Nabarlek and Koongarra in the Alligator Rivers region, Northern Territory, Australia. Single-pass ultrafiltration of large volumes with cut-offs of 18 nm and 1 m was used. Colloids were composed of Fe and Si species with sorbed U and U daughters. Uranium isotopes were mostly present as soluble species. Thorium was significantly associated with the colloids. The 234 U / 238 U activity ratios (ARs) were similar in solute and colloid phases close to the ore bodies but further down-gradient colloids were generally more depleted of 234 U than the solute. The 230 Th / 234 U ARs rose from very low values for both solute and colloid phases close to the ore bodies through several orders of magnitude to much higher values further down-gradient. Colloid 230 Th / 234 U ARs were always significantly greater than solute ARs. Results were consistent with a systematic leaching of U from colloids going down-gradient and very little mobilization of ore-body 230 Th relative to U. Ubiquitous complexed 232 Th appeared to suppress the solubility of 230 Th.

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