210Pb-derived history of PAH and PCB accumulation in sediments of a tropical inner lagoon (Las Matas, Gulf of Mexico) near a major oil refinery

Mathematics – Logic

Scientific paper

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

Scientific paper

Concentrations of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) were measured in a sediment core from the tropical freshwater inner lagoon of Las Matas, near the petroleum industrial area of Minatitlán-Coatzacoalcos, in the Gulf of Mexico. A 210Pb-derived chronology was used to reconstruct the historical PAH and PCB accumulation in the site during one century (1906-2005). Both geochemical and sedimentological data indicated that a major change occurred in 1947 ± 4, including a shift to coarser sediments and a significant decrease of Al, Li, Fe, organic C and total N contents. This was likely due to the changes in hydrology caused by the confinement of Las Matas Lagoon due to the construction of the Trans-Isthmus road in 1946. PAHs in these samples show relatively low concentrations (259-1176 ng g-1), and the congener relative abundances indicate the influence of pyrogenic (petroleum combustion) sources. Total PCB concentrations in the sediments ranged from 24 to 77 ng g-1, and are composed by low chlorinated PCBs, with 3- and 4-CB as the prevalent species (51-65% and 29-40%, respectively). PAHs and PCBs were detected at depths corresponding to the early 1900s, when Minatitlán refinery started operations, although their time evolution appears to be influenced by different accumulation processes. The PCB background is most likely produced by the combustion of natural organic matter, and an industrial contribution can be recognized when normalizing with OC contents. We concluded that atmospheric deposition is the most significant source of PAHs and PCBs for this water body. This study also provided evidence of the alteration of the wetlands surrounding this industrial area due to urbanization; the fragmentation and alteration of Las Matas Lagoon hydrology contributes to the gradual loss of the wetlands in the zone.

No associations

LandOfFree

Say what you really think

Search LandOfFree.com for scientists and scientific papers. Rate them and share your experience with other people.

Rating

210Pb-derived history of PAH and PCB accumulation in sediments of a tropical inner lagoon (Las Matas, Gulf of Mexico) near a major oil refinery does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with 210Pb-derived history of PAH and PCB accumulation in sediments of a tropical inner lagoon (Las Matas, Gulf of Mexico) near a major oil refinery, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and 210Pb-derived history of PAH and PCB accumulation in sediments of a tropical inner lagoon (Las Matas, Gulf of Mexico) near a major oil refinery will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFWR-SCP-O-1116466

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.