Stratospheric distribution of ClONO2

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Atmospheric Chemistry, Atmospheric Composition, Chlorine Oxides, Nitrogen Dioxide, Photochemical Reactions, Stratosphere, Absorption Spectra, Balloon-Borne Instruments, Infrared Spectra, Particle Size Distribution, Solar Spectra

Scientific paper

Balloon-borne infrared solar spectra in the 1292/cm region, at 0.02/cm resolution, obtained during sunset, are used to derive a mixing ratio altitude profile of ClONO2. Portions of the spectra covering the 1292/cm region are shown together with a laboratory spectrum of ClONO2 and HNO3 taken with a flight interferometer. The agreement of the atmospheric absorption feature in shape and position with the ClONO2 spectrum, along with the fact that the feature is not due to other known atmospheric compounds, results in the identification of the atmospheric absorption as being due to ClONO2.

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