A Newly Developed Model for Fluorescence of C2H6 ν5 in Comets and Application to Infrared Spectra Acquired with NIRSPEC at Keck II

Other

Scientific paper

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

Scientific paper

Exploring the compositional diversity of cometary nuclei is key to understanding the formation and evolution of the Solar System, and the origin of water and prebiotic organics on the Earth. For most polyatomic gases, a production rate can be obtained from measured ro-vibrational intensities if an accurate rotational temperature is available, and the comparison of temperatures displayed by individual molecular species can reveal additional insights into physics in the cometary inner coma. Until now, accurate temperatures could be derived for HCN, CO, and H2O, but not for ethane (C2H6). As a symmetric hydrocarbon, C2H6 is uniquely sampled in the infrared, but the fine rotational structure of the ν7 Q-branches at 3.3 μm cannot be resolved by current infrared spectrometers, ultimately limiting the retrievals of rotational temperatures from these lines. However, the complex ro-vibrational structure (P- and R-branches) of the ν5 band at 3.5 μm is resolved by the Near Infrared Echelle Spectrograph on the Keck II telescope (NIRSPEC). We developed a fluorescence model for the infrared ν5 band of C2H6, and applied it to interpret high-resolution infrared spectra acquired with NIRSPEC. We present rotational temperatures and production rates for C2H6 in multiple comets. We compare the extracted rotational temperatures for ethane with those obtained from simultaneous measurements of other species (H2O and HCN). We also compare mixing ratios derived from the C2H6 ν5 band with those derived from the previously analyzed (by NASA GSFC team members) ν7 band. This work now establishes a robust method for quantifying additional physical parameters for ethane in comets.

No associations

LandOfFree

Say what you really think

Search LandOfFree.com for scientists and scientific papers. Rate them and share your experience with other people.

Rating

A Newly Developed Model for Fluorescence of C2H6 ν5 in Comets and Application to Infrared Spectra Acquired with NIRSPEC at Keck II does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with A Newly Developed Model for Fluorescence of C2H6 ν5 in Comets and Application to Infrared Spectra Acquired with NIRSPEC at Keck II, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and A Newly Developed Model for Fluorescence of C2H6 ν5 in Comets and Application to Infrared Spectra Acquired with NIRSPEC at Keck II will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFWR-SCP-O-969358

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.