Other
Scientific paper
Jan 1996
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1996ammin..81..902w&link_type=abstract
American Mineralogist, vol. 81, p. 902
Other
5
Trace Elements, Lunar Soil, Zirconium, Technologies, Heavy Elements, Ion Probes, Rare Earth Elements, Degradation, Breccia, Dosage, Field Strength, Fluorescence, Laser Spectroscopy, Microanalysis, Minerals, Radiation Damage, Raman Spectra, Spectroscopic Analysis
Scientific paper
We have determined major (Si, Zr, Hf), minor (Al, Y, Fe, P), and trace element (Ca, Sc, Ti, Ba, REE, Th, U) concentrations and Raman spectra of a zoned, 200 microns zircon grain in lunar sample 14161,7069, a quartz monzodiorite breccia collected at the Apollo 14 site. Analyses were obtained on a thin section in situ with an ion microprobe, an electron microprobe, and a laser Raman microprobe. The zircon grain is optically zoned in birefringence, a reflection of variable (incomplete) metamictization resulting from zo- nation in U and Th concentrations. Variations in the concentrations of U and Th correlate strongly with those of other high-field-strength trace elements and with changes in Raman spectral parameters. Concentrations of U and Th range from 21 to 55 ppm and 6 to 31 ppm, respectively, and correlate with lower Raman peak intensities, wider Raman peaks, and shifted Si-O peak positions. Concentrations of heavy rare earth elements range over a factor of three to four and correlate with intensities of fluorescence peaks. Correlated variations in trace element concentrations reflect the original magmatic differentiation of the parental melt approx. 4 b.y. ago. Degradation of the zircon structure, as reflected by the observed Raman spectral parameters, has occurred in this sample over a range of alpha-decay event dose from approx. 5.2 x 1014 to 1.4 x 1015 decay events per milligram of zircon, as calculated from the U and Th concentrations. This dose is well below the approx. 1016 events per milligram cumulative dose that causes complete metamictization and indicates that laser Raman microprobe spectroscopy is an analytical technique that is very sensitive to the radiation-induced damage in zircon.
Jollife Bradley L.
Kremser Daniel T.
Wopenka Brigitte
Zinner Ernst
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