Chemical evolution and ammonia in the early earth's atmosphere

Mathematics – Logic

Scientific paper

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Ammonia, Atmospheric Chemistry, Chemical Evolution, Earth Atmosphere, Photochemical Reactions, Planetary Evolution, Primitive Earth Atmosphere, Atmospheric Composition, Biological Evolution, Nitrogen, Precambrian Period, Reduction (Chemistry), Titanium Oxides

Scientific paper

A constraint on research into the evolution of the earth's atmosphere may have been resolved by recent work on the photochemical reduction of atmospheric nitrogen by a naturally occurring form of TiO2. It is shown that this source could have provided a small but vital abiological supply of ammonia in the early atmosphere of the earth. Locally the levels of NH3 produced by this mechanism satisfy the requirements of origin-of-life biologists while global levels do not conflict with chemical and physical constraints on the surface/atmosphere system nor with geological evidence for early Precambrian conditions.

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