Quantum effects in the formation of CH/plus/ by radiative association

Details Quantum effects in the formation of CH/plus/ by radiative association Quantum effects in the formation of CH/plus/ by radiative association

Jul 1976

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1976apj...207l..69a&link_type=abstract

Astrophysical Journal, vol. 207, July 1, 1976, pt. 2, p. L69-L72.

Astronomy and Astrophysics

Astrophysics

17

Free Radicals, Hydrocarbons, Interstellar Matter, Molecular Interactions, Radiative Recombination, Recombination Coefficient, Abundance, Quantum Mechanics, Reaction Kinetics, Resonance, Temperature Effects, Wave Functions

Scientific paper

The rate coefficient for radiative association of CH/plus/ is calculated for temperatures ranging from 20 K to 1000 K with a quantum treatment including the rotational distortion of the nuclear wave functions. The sharp resonances arising in the process are systematically enumerated and located. They result in an enhancement of no more than 25 percent for the rate coefficient, in comparison with the semiclassical values.

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