Einstein coefficients for rotational lines of the (0,0) band of the NO A2sigma(+)-X2Pi system

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Electron Transitions, Molecular Spectroscopy, Nitric Oxide, Rotational Spectra, Absorption Spectroscopy, Ground State, Laser Induced Fluorescence, Molecular Excitation, Quantum Statistics, Spectral Line Width, Transition Probabilities

Scientific paper

A summary of the spectroscopic equations necessary for prediction of the molecular transition energies and the Einstein A and B coefficients for rovibronic lines of the gamma(0,0) band of nitric oxide (NO) is presented. The calculated molecular transition energies are all within 0.57/cm of published experimental values; in addition, over 95 percent of the calculated energies give agreement with measured results within 0.25/cm. Einstein coefficients are calculated from the band A00 value and the known Hoenl-London factors and are tabulated for individual rovibronic transitions in the NO A2sigma(+)-X2Pi(0,0) band.

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