The millimeter-wave spectrum and the dipole moment of vinylacetylene

Astronomy and Astrophysics – Astrophysics

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Molecular Data, Methods: Laboratory, Techniques: Spectroscopic, Stars: Agb And Post-Agb

Scientific paper

The pure rotational spectrum of the hydrocarbon vinylacetylene (1-butene-3-yne, H2C=CH-Cequiv CH) in its ground vibrational state has been investigated from 80 to 165 GHz, covering the rotational quantum numbers 8 <=J <=18 and 0 <=Ka <=17 , in order to provide accurate rest frequencies for radioastronomical searches. Moreover, quantum chemical calculations of the dipole moment components mu a and mu b have been performed leading to the result mu a~0.4 D. The value for the dipole moment component mu b is very low and lies in the range of several thousandth to a few hundredth of a Debeye.
Table 1 is only available in electronic at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/ A+A/398/L11

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