The visible bands of ammonia - Band strengths, curves of growth, and the spatial distribution of ammonia on Jupiter

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Ammonia, Jupiter Atmosphere, Spectral Bands, Altitude, Astronomical Spectroscopy, Spatial Distribution, Jupiter, Atmosphere, Ammonia, Bands, Distribution, Experiments, Spectrum, Methane, Element Ratios, Abundance, Wavelengths, Data, Procedure, Absorption, Observations, Carbon/Nitrogen, Latitudes, Pressure, Analysis, Resolution, Aerosols

Scientific paper

We report room-temperature laboratory studies of the 5520 Å (6ν1) and 6475 Å (5ν1) bands of self-broadened ammonia at column densities ranging from 1.7-435.7 meter-amagats (m-am). Detailed equivalent-width measurements at 24 different pressure-pathlength combinations corresponding to four pressures between 44 and 689 torr and pathlengths between 32 and 512 m are used to determine curves of growth and integrated band strengths. The band strengths for the (6ν1) and and 5ν1 overtones are 5520 Å: S = 0.096 ± 0.005 cm-1 (m-am)-1 and 6475 Å: S = 0.63 ± 0.03 cm-1 (m-am)-1, respectively.
Using these band strengths and curves of growth, we analyze new spatially resolved spectra of Jupiter showing a nonhomogeneous distribution of ammonia in the Jovian atmosphere. The observed variations in the CH4/NH3 mixing ratio are interpreted as evidence of altitude-dependent depletion of ammonia in the atmosphere.

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