Ion microprobe analysis of oxygen and carbon isotope ratios in the ALH84001 meteorite

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Chondrites, Carbon Isotopes, Ion Probes, Oxygen Isotopes, Carbonates, Silicates, Carbon 12, Carbon 13, Oxygen 18

Scientific paper

A Cameca ims 4f ion microprobe is used to analyze carbonate and silicate minerals in the Martian meteorite ALH84001 in situ for (O-18/(O-16) and (C-13)/(C-12). The present sample is composed predominantly of orthopyroxene with minor chromite, maskelynite, pyrite, SiO2, and multiple generations of carbonate, including disk-shaped carbonate concretions reported to contain submicroscopic grains of magnetite and greigite. Ten analyses of orthopyroxene show homogeneity at delta(O-18) = 4.6 +/- 1.3 mil pct. Chemical compositions of carbonate in ALH84001 are reported in the fields of low-temperature immiscibility of the Ca-Mg-Fe carbonate system.

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