Transition probabilities in the C2Sigma(+)-X2Pi system of CH

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Flame Spectroscopy, Free Radicals, Hydrocarbon Combustion, Laser Induced Fluorescence, Transition Probabilities, Combustion Chemistry, Dipole Moments, Ground State, Oscillator Strengths, Wave Functions

Scientific paper

Relative Einstein emission coefficients are measured for several bands of the C2Sigma(+)-X2Pi system of the CH radical, using laser-induced fluorescence in an atmospheric pressure flame. The results are compared with theoretical calculations; a previously calculated ab initio electronic transition moment, together with Morse wave functions, forms an excellent representation of the experimental results.

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