The photodissociation lifetimes of the NH radical in comets

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Comets, Free Radicals, Gas Dissociation, Imides, Photodissociation, Life (Durability), Radial Velocity, Velocity Distribution, Comets, Photodissociation, Nh Radical, Solar Radiation, Calculations, Velocity, Distance, Parent Molecules, Nitrogen, Hydrogen, Bennett, Ammonia, Distribution

Scientific paper

The authors present photodissociation rates of NH by absorption of solar radiation into the υarcmin = 2 level of the A3Πi state as a function of radial velocity for a comet at a heliocentric distance of 1 AU. The photodissociation of NH results in velocity distributions of about 1 km s-1 and 15 km s-1 for nitrogen and hydrogen atoms, respectively, with respect to NH. By comparing the convolution model lifetime of the NH parent for comet Bennett (1970 II) with the photochemical lifetime of NH3 against solar photon flux at 1 AU the authors infer that NH3 is probably the parent of NH radical observed in comets.

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