Diffuse Reflectance Circular Dichroism for the Detection of Molecular Chirality: An Application in Remote Sensing of Flora

Astronomy and Astrophysics – Astronomy

Scientific paper

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Scientific paper

Terrestrial biochemistry is based upon chiral (handed) molecules, of which only one of the two possible hands is predominantly employed. This biomolecular ``homochirality'', may be a universal ``signature'' of life. Along with all living organisms, plant leaves are constructed from arrays of chiral molecules of a single hand. Through the development of a new spectroscopic approach, Diffuse Reflectance Circular Dichroism in the UV-visible wavelength regions, we have detected this chirality non-invasively from non-specular light scattered by leaves. The characteristic spectra are sensitive to plant species and leaf age/health. The technique may provide a means of remote sensing the state of flora and, at closer range, an indicator of living organisms for interplanetary landers.

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